R - Concatenate two dataframes?

Given two data frames a and b:

> a
           a           b           c
1 -0.2246894 -1.48167912 -1.65099363
2  0.5559320 -0.87898575 -0.15634590
3  1.8469466 -0.01487524 -0.53098215
4 -0.6875051  0.23880967  0.01824621
5 -0.6735163  0.75485292  0.44154092
> b
           a          c
1  0.4287284 -0.3295925
2  0.5201492  0.3341251
3 -2.6355570  1.7916780
4 -1.3645337  1.3642276
5 -0.4954542 -0.6660001

Is there a simple way to concatenate these so as to return a new data frame of the form below?

> new
           a                   b           c
1  -0.2246894   -1.48167912106676 -1.65099363
2   0.5559320  -0.878985746842256 -0.15634590
3   1.8469466 -0.0148752354840942 -0.53098215
4  -0.6875051   0.238809666690982  0.01824621
5  -0.6735163   0.754852923524198  0.44154092
6   0.4287284                  NA -0.32959248
7   0.5201492                  NA  0.33412510
8  -2.6355570                  NA  1.79167801
9  -1.3645337                  NA  1.36422764
10 -0.4954542                  NA -0.66600006

I want to merge the data frames, match the headers and insert NA in for positions in data frame b where the header is missing.